Non-steady-state model for kinetics of free radical polymerization, 4. Direct thermal initiation

This paper deals with the non-steady-state kinetics of direct thermal initiated polymerization. The initiation is assumed to be a bimolecular reaction of the monomer. The relationship between the radical concentration and the monomer conversion is rigorously derived. In further treatment a few very close approximations are introduced based on the fact that the number of monomer molecules reacting in the initiation step is much less than that consumed in the propagation step for a process producing high polymer, and the value of the rate constant for propagation or chain transfer is much lower than that for chain termination. Expressions for various molecular parameters, such as molecular weight distribution, number-average and weight-average degrees of polymerization, and dispersity, are given. Several numerical examples are provided.     

铸造Ti—0.2Pd合金SF—1000双级风机叶轮的研制

Ｔｉ－０．２Ｐｄ合金ＳＦ－１０００双级风机叶轮是大型盐酸再生设备的主要部件，采用整体铸造方法制造，无论在技术上还是经济上都是十分有利的。本文主要介绍采用加工石墨，铸铁组合型，真空电弧凝壳熔炼铸造工艺，成功地研制出整体铸造风机叶轮。     

旋波媒质基本参数的一种测试方法

本文提出了直接利用旋波材料板的Ｓ参数获得其基本参数的方法。通过自由空间测量旋波材料板的反射场和透射场，可以反演得到媒质的复介电常数、复磁导率、旋波量以及透射场的轴比和旋转角，测试程序简单，结果精度高。     

哈拉沁水库泄洪洞进水塔静动力分析

利用4—21节点块体单元对哈拉沁水库泄洪洞进水塔进行离散,分析6种工况下进水塔结构的自振特性，并通过反映谱法计算顺水向和垂直水向结构的抗震动力响应，包括结构的动位移和动应力。将动力计算结果与静力计算结果进行叠加，成果显示进水塔的变形和强度均满足要求，为工程设计提供了依据。     

Lowering the erosion wear of long blades of the last stages by optimum hanging

Problems of optimum hanging of long rotor blades of the last stages of steam turbines are considered. Causes of nonuniform erosion wear of the inlet edges connected with inaccurate location of holes for the external damper coupling on the chord of the profile are determined. Methods for optimizing the hanging of blades for raising the reliability of the last stages are suggested. Main results of hanging performed with the help of a specially developed “LIBRA” soft hardware are presented. __________ Translated from élektricheskie Stantsii, No. 11, November 2006, pp. 36–41.     

节理岩体的代表单元集合体模型及弹性参数预测

本文明确提出了节理岩体“代表单元集合体”的概念和模型，通过对节理岩体的“代表单元集合体”进行数值模拟，研究了节理岩体的“代表单元集合体”的变形特性，建立了节理岩体的弹性模型，提出了预测节理岩体宏观等效弹性参数的计算机模拟方法，并将其应用于岩体工程稳定性分析中。     

Hydrolytic stability and protective properties of polyurethane oligomers based on polyester/ether/polyols

The present study deals with effect of the type and chemical character of incorporated polyester/polyether blocks on the hydrolytic stability of crosslinked polyurethane oligomers. Diffusion parameters of the investigated polyurethane oligomers, giving information concerning chemical changes taking place in neutral, basic and acidic aqueous environments, have also been determined.     

从头算法对甲基磺酸拉曼光谱振动频率指认

对液态的甲基磺酸进行了拉曼光谱测定。采取从头算法用各种不同的基组 (最大的基组为MP2 / 6 -311+G( 2d ,2 p) )对甲基磺酸的结构和光谱进行了计算 ,得到了甲基磺酸的结构参数及稳定构象信息。采用一个具有Ci 对称的二聚体模型解释了甲基磺酸的液态光谱。对单体和二聚体的甲基磺酸进行了简正坐标计算 ,结果表明二聚体结构是液态甲基磺酸聚积态分子的合理模型。